Is your copy of Windows XP legit? If it is, then it should give you the option to boot from it. All Windows XP CDs have the ability to boot off the CD.
You can actually choose the boot order of your devices in the Sony BIOS. You’ll need to hit F2 (might need to repeatedly press this so you don’t miss it) when you see the VAIO logo.
Once inside the BIOS, you should make sure that the CD/Optical drive is the first choice. On mine, I have CD first, Floppy second, and HD third.