Good luck getting any answers out of Sony tech support about compatability with anything remotely complex. Their support site is useless. FWIW, I know that the Centrino cards are WPA-compatable as long as you install the WPA update from MS (and the driver on the Sony site for TR1s). I believe they also work with LEAP.
The mini PCI card is technically upgradeable. I’ve read about people popping the mini PCI cards out of 802.11g-capable Linksys routers and putting them in their Centrino-based laptops, but it also required a driver install. IIRC this makes the modem useless. YMMV.
I have a TR1A, and it takes me on average less than 15 sec to boot from hibernation and about 25 sec to hibernate. Much better than cold booting, but nowhere near PDA speeds. Honestly, I find it faster to boot than to take the thing out of my bag and fiddle with the BT dongle. :?